Officers from the Metropolitan Police's Central Task Force stopped the silver Vauxhall Vectra in Sudbury Drive, Wembley, which contained 51 kilos of the drug stuffed inside four cardboard boxes.
Class B Cathinone Derivative - nicknamed 'Meow Meow' - has been linked to several deaths and seizures amongst young people.
The 26 year old male driver of the car was arrested on suspicion of possession, with intent to supply, the drug and was taken into police custody.
Detective Inspector Colin Stephenson said: "This arrest and seizure has disrupted a significant supply of Meow Meow within London and the Home Counties.
"It will reinforce the message that the Metropolitan Police Service will continue to combat the criminal networks engaged in drug trafficking"
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